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http://nopr.niscpr.res.in/handle/123456789/18308| Title: | Synthesis and reactivity of the copper (II) complexes of N-α-acetophenyl-X-salicylaldimines (α = 4 or 3, X = H, 5-Br or 3-COOH ). Molecular structure of bis-(N-4-acetophenyl-salicylaldiminato) copper(II) |
| Authors: | De, Rajib Lal Banerjee, Indrajit Guha, Subhadra Mukherjee, Alok K |
| Issue Date: | Jul-2002 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The copper (II) complexes of the Schiff bases, N-α-acetophenyl-X-salicylaldimines (α = 4 or 3, X = H, 5-Br or 3-COOH) have been synthesised and characterised by UV-visible, IR, MS, ESR spectroscopy and magnetic susceptibility measurements. The solid state structure of Cu(SACPNx)2 (I) determined by single-crystal X-ray diffraction reveals a distorted square-planar metal coordination involving two imine N- and two deprotonated phenolate O atoms of two bidentate Schiff ligands in trans- arrangement. Both the Schiff bases and their copper (II) complexes undergo facile transamination reactions. |
| Page(s): | 1380-1384 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.41A(07) [July 2002] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 41A(7) 1380-1384.pdf | 1.02 MB | Adobe PDF | View/Open |
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