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http://nopr.niscpr.res.in/handle/123456789/18583| Title: | Synthesis and crystal structure of a linear polymeric tributyltin 4-pyridinecarboxylate |
| Authors: | Yin, Handong Wang, Chuanhua Wang, Yong Ma, Chunlin |
| Issue Date: | Oct-2001 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The complex tributyltin 4-pyridinecarboxylate has been synthesized by the reaction of tributyltin chloride with sodium 4- pyridinecarboxylate in benzene and characterized by IR, 1H NMR, elemental analyses, MS and X-ray structural analyses. The crystals are monoclinic, space group P21/c, with a=9.6673 (14), b=23.845 (4), c=9.7071 (14) Å; β=112.463 (3)°; V=2067.9(5) Å3 , Z=4, Dc= 1.324 Mg m-3, μ=1.242 mm-1, F(000)=848, R1=0.0544, WR2=0.1411. In the crystals, the tin atoms are rendered five- coordinate in a trigonal bipyramidal structure by coordinating with 4-pyridinylearboxlate group. The resulting structure is a linear polymer containing Sn-O and Sn-N bonds whose lengths are 2.170 (5) Å and 2.60 (2) Å, respectively. |
| Page(s): | 1089-1092 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.40A(10) [October 2001] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 40A(10) 1089-1092.pdf | 897.1 kB | Adobe PDF | View/Open |
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