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http://nopr.niscpr.res.in/handle/123456789/26069| Title: | Kinetics and mechanism of oxidation of 2-hydroxycyclohexanone by vanadium (V) |
| Authors: | Panigrahi, G P Swain, Rajendra |
| Issue Date: | Jul-2000 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Reaction of 2-hydroxycyclohexanone with vanadium (V) in aq. acetic acid containing HClO4 is first order each with respect to [V (V)] and [H+]. The dependence on [2-hydroxycyclohexanone] is two. Substrate oxidant stoichiometry is observed to be 1:2. Decomposition of a complex formed between two molecules of 2-hydroxycyclohexanone and one molecule of V(V) has been proposed as the slow step. |
| Page(s): | 775-778 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.39A(07) [July 2000] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 39A(7) 775-778.pdf | 2.82 MB | Adobe PDF | View/Open |
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