Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/29343
Title: Methyl termination and ATR-FTIR evaluation of n-Si (111) electrode towards photoelectrochemical cell fabrication
Authors: Ohtake, Toshihito
Keywords: Methyl termination;ATR-FTIR;Semiconductor electrode;Si;Photoelectrochemical cell
Issue Date: Sep-2014
Publisher: NISCAIR-CSIR, India
Abstract: We confirmed methyl termination on n-Si(111) surface by ATR-FTIR measurement, which was fabricated by a photo chloro-reaction and its methylation. The coverage of the methylation was about 63.7 %, and the surface was not re-terminated by hydrogen. Photoelectrochemical properties of the n-Si(111) was measured as an electrode for a photoelectrochemical cell, and an onset potential obtaining photocurrent for the methyl terminated n-Si(111) electrode was observed as negative shift at 70 mV comparing with that of the hydrogen terminated n-Si(111) electrode. Therefore, the negative shift would be expected for improving open circuit voltage towards solar cell.
Page(s): 598-600
ISSN: 0975-1084 (Online); 0022-4456 (Print)
Appears in Collections:JSIR Vol.73(09) [September 2014]

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