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http://nopr.niscpr.res.in/handle/123456789/40147| Title: | Kinetics of oxidation of organic sulphides with carboxylato-bound Chromium(V) |
| Authors: | Ganesan, T K Bharathy, J R Bosco Sheriff, A I Md Rajagopal, S |
| Issue Date: | Jul-1995 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Carboxylato-bound Cr(V) oxidation of aryl methyl sulphides (ArSMe) proceeds through a complex formation between the oxidant and substrate. The peculiar substituent effect observed is attributed to the reaction being carried out at a temperature close to the isokinetic temperature. Comparison of the kinetic results observed with-Cr(V) and Cr(VI) oxidations points out the operation of different mechanisms-single electron transfer in Cr(VI) oxidation and complex formation followed by ligand coupling in Cr(V) oxidation. |
| Page(s): | 522-528 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.34A(07) [July 1995] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 34A(7) 522-528.pdf | 1.88 MB | Adobe PDF | View/Open |
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