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http://nopr.niscpr.res.in/handle/123456789/40480| Title: | Synthesis and characterization of platinum metal complexes of dibenzyl sulphoxide and tetramethylene sulphoxide |
| Authors: | Bora, Tankeswar Hazarika, Dimbeswar |
| Issue Date: | Mar-1994 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Tetramethylene sulphoxide (TMSO) and dibenzyl sulphoxide (DBSO) use sulphur or oxygen or both as donor sites. Platinum metal chlorides are found to form complexes of the types, ML3Cl3 [where M = Ru(III), Rh(III), Ir(III), L = TMSO, DBSO] and platinum(II) yields the complex Pt(DBSO)2Cl2. The compounds have been characterized by elemental analyses, molar conductance measurements and IR spectral analysis. Fac- structures has been assigned for ML3Cl3 but mer- is found for Ru2(DBSO)4CI6 and Rh(DBSO)3Cl3 The ESR spectra reveal axial distortion with g1 = 2.192 and g2 = 1.892 for Ru2(DBSO)3CI3 and g = 2. 172 for Ru(TMSO)3CI3. |
| Page(s): | 269-271 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.33A(03) [March 1994] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 33A(3) 269-271.pdf | 219.04 kB | Adobe PDF | View/Open |
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