Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/41304| Title: | Synthesis and characterisation of cis-dioxomolybdenum(VI) Schiff base complexes derived from 2-benzoylpyridine |
| Authors: | Maurya, R C Mishra, D D Rao, N S Verma, R Rao, N N |
| Issue Date: | Jul-1997 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | cis-Dioxomolybdenum(VI) complexes of bi-, tri- and tetra-dentate Schiff bases derived from 2-benzoylpyridine and monoamines, such as, p-anisidine, m-phenetidine or p-toluidine, and diamines, viz., o-, mor p-phenylenediamine are reported. Reactions of the bi-, tri- and tetradentate Schiff bases with [MoO2(acac)2] in ethanol medium in 1: 1, 1: 2 and 1 : 2 molar ratios, respectively, yield diamagnetic molybdenum(VI) monometallic complexes of the composition, cis-[MoO2(L)(OEt)2] (where L= bidentate schiff base derived from monoamine) and the ligand bridged bimetallic complexes, cis-[Mo2O4(L1 )(OEt)4] (where L1 = tridentate schiff base derived from o- or m-phenylenediamine or tetradentate schiff base with p-phenylenediamine). These complexes have been characterized by elemental analyses, molar conductances, IR, UViVis, 1H NMR and CV studies. |
| Page(s): | 599-601 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.36A(07) [July 1997] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 36A(7) 599-601.pdf | 748.64 kB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.