Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/41397| Title: | Synthesis and characterization of some unsymmetrical borole complexes |
| Authors: | Saxena, Chitra Singh, R V |
| Issue Date: | Aug-1996 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Reaction of unsymmetrical 2-isopropoxybenzo- 1,3-dioxa-2-borole with semi- and thiosemicarbazones of heterocyclic methyl ketones in benzene solution give different types of complexes with general formula [ (ln)], where Ln, is the deprotonated form of the ligand LnH; n = 1-8). The spectroscopic results show that the Iigands behave in a bidentate fashion whereas the complexes display a tetracoordinated environment around boron as stereochemically active lone pair is also included in the coordination sphere. |
| Page(s): | 707-709 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.35A(08) [August 1996] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 35A(8) 707-709.pdf | 570.89 kB | Adobe PDF | View/Open |
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(ln)], where Ln, is the deprotonated form of the ligand LnH; n = 1-8). The spectroscopic results show that the Iigands behave in a bidentate fashion whereas the complexes display a tetracoordinated environment around boron as stereochemically active lone pair is also included in the coordination sphere.