Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/41831| Title: | Synthesis and characterization of metal complexes with a schiff base formed by condensation of S-benzyl dithiocarbazate with isatin (H2IBD) |
| Authors: | EI-Reash, G M Abu Taha, Fim Shallahy, A M EI-Gamal, O A |
| Issue Date: | Mar-1991 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Synthesis and characterization of Mn(II), Co(II), Ni(II)., Zn(II), Cd(II), Hg(II) and UO complexes of isatin- hydrazone-S-benzyldithiocarbazate (H2IBD) are reported. Elemental analysis, molar conductance, magnetic moment and spectral (IR, visible, NMR) data have been used to characterize the complexes. IR spectral data show that the ligand behaves in a bidentate, tridentate or tetradentate manner in different complexes. An octahedral structure is proposed for the Mn(II), Co(II) and Ni(II) complexes while a square-planar structure is proposed for Cu(II)complexes on the basis of magnetic and spectral measurements. |
| Page(s): | 286-289 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.30A(03) [March 1991] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 30A(3) 286-289.pdf | 278.06 kB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.
complexes of isatin- hydrazone-S-benzyldithiocarbazate (H2IBD) are reported. Elemental analysis, molar conductance, magnetic moment and spectral (IR, visible, NMR) data have been used to characterize the complexes. IR spectral data show that the ligand behaves in a bidentate, tridentate or tetradentate manner in different complexes. An octahedral structure is proposed for the Mn(II), Co(II) and Ni(II) complexes while a square-planar structure is proposed for Cu(II)complexes on the basis of magnetic and spectral measurements.