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http://nopr.niscpr.res.in/handle/123456789/42037| Title: | electron-transfer reactions of Aquothallium(III) and coordinated thallium(III), oxidation of malonic acid with thallium(III) in perchlorate medium |
| Authors: | Rao, (Miss) Indu Mishra, S K Sharma, P D |
| Issue Date: | Sep-1991 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The reaction between thallium(III) and malonic acid (H2ma) studied in acid perchlorate medium corresponds to th stoichiometry as represented by the equation 3TI(III) + CH2(COOH)2 ®3TI(I) + HCOOH + CO2 + 6H+ Thallium(III) forms an intermediate complex and the reduction of thallium(III) occurs via an internal redox reaction of the complex. A suitable mechanism has been suggested and the energy and entropy of activation of the rat determining step have been calculated. |
| Page(s): | 773-776 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.30A(09) [September 1991] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 30A(9) 773-776.pdf | 824.35 kB | Adobe PDF | View/Open |
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