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http://nopr.niscpr.res.in/handle/123456789/42166| Title: | Kinetics and mechanism of oxidation of oxalic acid by iodate in aqueous sulphuric acid medium |
| Authors: | Ramana, P V Rao, R V Appa |
| Issue Date: | Nov-1991 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The oxidation of oxalic acid by iodate in aqueous sulphuric acidmedium proceeds with a measurable rate only at 60°C and above. Two paths (1) involving HIO3 and OXH2 and (2) HIO3 and OXH- have been found to be significant at [H+]< 1:0 mol dm-3 and path (1) only at [H+] > 1.0 mol dm-3. A single step two electron transfer mechanism is suggested. |
| Page(s): | 971-973 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.30A(11) [November 1991] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 30A(11) 971-973.pdf | 430.77 kB | Adobe PDF | View/Open |
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