Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/43806| Title: | Facile regeneration of carbonyl compounds from anils by manganese(III) triacetate- A kinetic study |
| Authors: | Srinivasan, Vangalur S Ramakrishnan, Kalyani |
| Issue Date: | Apr-1993 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The kinetics of regeneration of carbonyl compounds from anil of benzaldehyde and benzophenone by MnIII(OAc)3 have been studied at 29 ± 0.1ᵒC in aq. acetic acid (76%, v/v). The corresponding aldehyde/ketone is formed in about 96% yield along with nearly 48% of
azobenzene in about 3-4 hr. One mol of anil consumes nearly 2 mol of MnIII(OAc)3 for the reaction. The reaction is less susceptible to the electronic influence of substituents
on both benzaldehyde and aniline portions. A mechanism involving addition of MnIII(OAc)3 to C = N in the rate determining step has been envisaged to account for the results. |
| Page(s): | 338-340 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.32A(04) [April 1993] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 32A(4) 338-340.pdf | 171.27 kB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.