Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/44035| Title: | Kinetics of oxidation of substituted 2-phenylthiazolidines by pyridinium chlorochromate |
| Authors: | Ananthakrishnanadar, P Prabhakaran, T R |
| Issue Date: | Oct-1993 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Kinetics of oxidation of 2-phenylthiazolidine (PT) and substituted PI (SPT) by pyridinium chlorochromate (PCC) in dry acetic acid have been investigated. The reaction is first order in FCC and fractional order in PT and it exhibits Michaelis-Menten kinetic character. The complex formation constants (K) and the decomposition rate constants (k1) have been computed from the double reciprocal plots of 1/kobs versus 1/[PT]0. The decomposition rate constants are not correlated by Hammett σ constants. Nevertheless, they show satisfactory correlation with σ1 and σ2 parameters. The correlation with Swain and Lupton F and R values is relatively less satisfactory. |
| Page(s): | 877-880 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.32A(10) [October 1993] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 32A(10) 877-880.pdf | 274.09 kB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.