Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/44073| Title: | Chromium(VI) oxidation of antimony(III) in an aqueous alkaline medium |
| Authors: | Hugar, G H Nandibewoor, S T Raju, J R |
| Issue Date: | Dec-1993 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Chromium(VI) oxidation of antimony(III) in an alkaline medium follows a second order rate law with negative fractional dependence on [OH-]. The active species are CrO and SbO+ and the negative dependence on [OH-] is due to the formation of SbO+ from antimony hydroxide species. The effect of ionic strength, solvent polarity, added complexing agent and ions is also studied. Activation parameters have also been evaluated. |
| Page(s): | 1095-1098 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.32A(12) [December 1993] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 32A(12) 1095-1098.pdf | 252.21 kB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.