Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/46025| Title: | Kinetics of oxidation of bis(2,2',6',2"-terpyridine)iron(II) by cerium(IV) |
| Authors: | Satyanarayana, T Anipindi, N R Subbiah, V Pandit, M W |
| Issue Date: | Feb-1992 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The oxidation of bis(2,2',6',2"-terpyridine)iron(II), Fe(tpy) by cerium(IV) has been studied in sulphuric acid using stopped-flow spectrophotometry. The reaction is overall second order, first order in each reactant. The rate of the reaction increases with increase in [H2OSO].Three cerium (IV) species viz., CeSO , Ce(SO4)2 and Ce(SO4) are considered to be the reactive oxidising species. |
| Page(s): | 125-127 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.31A(02) [February 1992] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 31A(2) 125-127.pdf | 2.08 MB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.
, Ce(SO4)2 and Ce(SO4)
are considered to be the reactive oxidising species.