Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/46025
Title: Kinetics of oxidation of bis(2,2',6',2"-terpyridine)iron(II) by cerium(IV)
Authors: Satyanarayana, T
Anipindi, N R
Subbiah, V
Pandit, M W
Issue Date: Feb-1992
Publisher: NISCAIR-CSIR, India
Abstract: The oxidation of bis(2,2',6',2"-terpyridine)iron(II), Fe(tpy) by cerium(IV) has been studied in sulphuric acid using stopped-flow spectrophotometry. The reaction is overall second order, first order in each reactant. The rate of the reaction increases with increase in [H2OSO].Three cerium (IV) species viz., CeSO, Ce(SO4)2 and Ce(SO4) are considered to be the reactive oxidising species.
Page(s): 125-127
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.31A(02) [February 1992]

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