Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/46199| Title: | σ-Bonded organometallics of iron and their facile conversion into π complexes |
| Authors: | Ahmed, I Ahmad, J U Karim, M M Sarder, S I Ullah, S S |
| Issue Date: | Sep-1992 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The metal carbonylate anion, Na[Fe(η5-C5H5)(CO)] reacts at room temperature with halogeno organic ligands 1,3,5-tris(bromomethyl)benzene and 1,2,4,5-tetrakis-(bromomethyl)benzene to give the complexes 1,3,5-tris- (σ-methylene) benzene {tris(η5-cyciopentadienyl)hexacarbonyliron} (1) and 1,2,4,5-tetrakis(σ-methylene) benzene {tetrakis(η5-cyclopentadienyl) octacarbonyliron} (3). The complex (1) undergoes thermal transformation to the corresponding π complex whereas, complex (3) does not due to the 18-electron rule formalism. |
| Page(s): | 699-701 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.31A(09) [September 1992] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 31A(9) 699-701.pdf | 339.78 kB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.