Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/46212| Title: | Synthesized and characterization of oxomolybdenum(V) complex with dithiooxamide |
| Authors: | Lakshmanan, Vasanthi Nagaraja, K.S. Udupa, M R |
| Issue Date: | Oct-1992 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The complex Mo2O4(dto)2 (dto = dithiooxamide) has a magnetic moment of 0.51B.M. The electronic spectral data (450 nm) indicate the presence of Mo2O42+ core. The negative shifts (50 cm-1) and spitting in v(CN) and v(CS) bands indicate the uninegative bidentate nature of dithiooxamide. The bands at 970, 740 and 480 cm-1 indicate the presence of terminal (Mo=O1) and bridging (MoOb) Mo groups. The complex exhibits and irreversible cathodic wave (-1.30 vs SCE) characteristic of a Mo2O42+ core. A di-μ-oxo bridged structure with dithiooxamide completing five coordination around each Mo is proposed. |
| Page(s): | 806-807 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.31A(10) [October 1992] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 31A(10) 806-807.pdf | 57.25 kB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.