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http://nopr.niscpr.res.in/handle/123456789/46255| Title: | Kinetics and mechanism of oxidation of serine, threonine, arginine, aspartic acid and glutamic acid by N-bromoacetamide in alkaline medium |
| Authors: | Reddy, M Komal Sribabu, Ch Sundaram, E V |
| Issue Date: | Jan-1990 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The title amino acids are oxidised to the corresponding aldehydes, ammonia and carbon dioxide. The effect of varying [substrate], [oxidant], [OH-] and ionic strength have been studied. The data reveal that the reaction is first order in [NBA] and fractional order each in [substrate] and [OH-]. Addition of acetamide does not affect the rate of oxidation. Thermodynamic parameters have been calculated and a suitable mechanism consistent with the experimental results is proposed. |
| Page(s): | 61-62 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.29A(01) [January 1990] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 29A(1) 61-62.pdf | 488.04 kB | Adobe PDF | View/Open |
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