Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/46286| Title: | Reactions of NOX (X =CI, Br, Br3) with cyclopentadienyl complexes of ruthenium |
| Authors: | Gupta, Minu Seth, Jyoti Agarwala, U C |
| Issue Date: | Feb-1990 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | η5-Cyclopentadienylruthenium (II) complexes [Ru(η5-C5H5)-(EPh3)L-L]X or [Ru(η5- C5H5)X(EPh3)L] (where E=As, Sb; (L-L) = 2,2'-bipy, 1,10-phen; L = py, γ-Pic, SbPh3, PPh3 and X=CI, Br, I, CN, NCS) undergo oxidative addition reactions with NOX (X = Cl-, Br-, Br ) yielding ruthenium (II) nitrosyl derivatives, wherein NO binds with the metal as NO+, a terminal and' linear mode of bonding. All the complexes have been characterized by various physicochemical methods. |
| Page(s): | 143-149 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.29A(02) [February 1990] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 29A(2) 143-149.pdf | 495.69 kB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.