Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/46307| Title: | A CNDO/2 model system [Ru(NX)(NH2)4Cl]2- (X = O,S): Comparison of electronic structure of Ru-NO and Ru-NS complexes |
| Authors: | Pandey, K K Massoudipour, M Paleria, V |
| Issue Date: | Mar-1990 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The computed trends of Ru-N, NS and NO bond strengths in the title complexes, as measured by Wiberg indices. charge distribution and orbital populations suggest that the strength of the Ru-NS bond is greater than that of Ru-NO bond, and NS ligand is a better electron acceptor from the central metal atom than NO ligand. The strength of Ru-CI bond trans to NS ligand is weaker than that of the Ru-CI bond trans to NO ligand. The ratio of σ donor to π acceptor abilities of NS ligand is greater than that of the NO ligand. |
| Page(s): | 260-262 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.29A(03) [March 1990] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 29A(3) 260-262.pdf | 182.8 kB | Adobe PDF | View/Open |
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