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http://nopr.niscpr.res.in/handle/123456789/46669| Title: | Ruthenium{II} & rhodiurrul) complexes of 2-hydroxypyridinest |
| Authors: | Gopinathan, (Mrs) Sarada Unni, I R Gopinathan, C |
| Issue Date: | Apr-1989 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Ruthenium(II) and rhodiumil) precursors namely RuHCl(CO)(PPh3)3], [Ru(CO)2Cl2]n, [RuCl2(PPh3)3] and [RhH(PPh3)4 react with 2-hydroxypyridine (PyOH) and 6-methyl-2-hydroxypyridine (MePyOH) to afford a range of novel mononuclear complexes, namely [RuCl(CO)(PyO)(PPh3)2], [RuH(CO)(PyO)(PPh3)2], [RuCl(CO)(MePyO)(PPh3)2], [RuH(CO)(MePyO)(PPh3)2], [Ru(MePyO)2(PPh3)2], [Ru(CO)2(PyO)2], [Rh(PyO)(PPh3)2] and [Rh(MePyO)(PPh3)2]. In these complexes the oxypyridines are bound in bidentate (N,O-chelate) mode. The complexes have been characterized by analytical, IR and 1H NMR data. Evidences indicate that [RuH/Cl(CO)(PyO/MePyO)(PPh3)2] complexes exist in two geometrical isomeric forms. |
| Page(s): | 331-332 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.28A(04) [April 1989] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 28A(4) 331-332.pdf | 1.35 MB | Adobe PDF | View/Open |
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