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http://nopr.niscpr.res.in/handle/123456789/46718| Title: | Kinetics of silver(I) catalysed peroxydisulphate oxidation of benzylphenyl-glycollic Acids |
| Authors: | Mishra, Pranati Khandual, N C |
| Issue Date: | Jun-1989 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Ag(I) catalysed peroxydisulphate oxidation of benzylphenylglycollic and substituted benzylphenylglycollic acids in acetic acid-water mixture (30% v/v) at constant ionic strength is first order each in [peroxydisulphate] and [Ag(I)] and independent of [reductant]. Addition of allyl acetate inhibits the reaction. The thermodynamic parameters have been evaluated. The log k1 values have been fitted With σ+ values and the value of ρ+ calculated. The rate laws have been proposed on the basis of free radical mechanism involving silver(I). |
| Page(s): | 523-525 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.28A(06) [June 1989] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 28A(6) 523-525.pdf | 1.93 MB | Adobe PDF | View/Open |
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