Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/46801
Title: Solvent effects on the electronic spectrum of mesityl oxide
Authors: Bhat, S N
Gupta, Kailash
Issue Date: Sep-1989
Publisher: NISCAIR-CSIR, India
Abstract: The π-π* transition of mesityl oxide, a polar solute, exhibits a red shift in polar and hydrogen-bonding solvents while n-π* transition exhibits a blue shift. A good linear relationship exists between D v, the shift in frequency (for π-π* as well as n-π* transitions) and n, the refractive index of the solvent rather than D, its dielectric .constant. A systemetic variation of v with the increase in D is observed when dielectric constant of the medium is varied by changing the composition of the solvents in solvent mixtures.
Page(s): 787-789
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.28A(09) [September 1989]

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