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http://nopr.niscpr.res.in/handle/123456789/46801| Title: | Solvent effects on the electronic spectrum of mesityl oxide |
| Authors: | Bhat, S N Gupta, Kailash |
| Issue Date: | Sep-1989 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The π-π* transition of mesityl oxide, a polar solute, exhibits a red shift in polar and hydrogen-bonding solvents while n-π* transition exhibits a blue shift. A good linear relationship exists between D v, the shift in frequency (for π-π* as well as n-π* transitions) and n, the refractive index of the solvent rather than D, its dielectric .constant. A systemetic variation of v with the increase in D is observed when dielectric constant of the medium is varied by changing the composition of the solvents in solvent mixtures. |
| Page(s): | 787-789 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.28A(09) [September 1989] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 28A(9) 787-789.pdf | 1.86 MB | Adobe PDF | View/Open |
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v with the increase in D is observed when dielectric constant of the medium is varied by changing the composition of the solvents in solvent mixtures.