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http://nopr.niscpr.res.in/handle/123456789/51188| Title: | Synthesis and Electrochemical Analysis of Biologically Active Novel NiIIHMTAA and CuIIHMTAA Complexes |
| Authors: | Vashistha, V K Kumar, Y Kumar, A Das, D K |
| Keywords: | Template method;Macrocycles;Spectral studies;Cyclic voltammetry;Antibacterial activity |
| Issue Date: | Nov-2019 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | NiIIHMTAA-14 and CuIIHMTAA-14 (HMTAA-14 = dichloro[2,4,9,13,15,20-hexamethyldibenzo-1,4,8,11-tetraazacyclotetradecatetraene]) macrocyclic complexes have been synthesized by template method and characterized by multiple characterization techniques. Electrochemical studies of NiIIHMTAA-14 and CuIIHMTAA-14 macrocyclic complexes carried out on Pt disc (tip-06.1204.120.) electrode (2 mm diameter) in methanol, DMSO and acetonitrile by employing cyclic voltammetry revealing that these macrocycles undergo one-electron electrochemical processes to form stable Ni(HMTAA)0 and Cu(HMTAA)+ species. Preliminary investigation of antimicrobial activities of these novel macrocyclic complexes has also been studied. |
| Page(s): | 788-792 |
| ISSN: | 0975-1084 (Online); 0022-4456 (Print) |
| Appears in Collections: | JSIR Vol.78(11) [November 2019] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| JSIR 78(11) 788-792.pdf | 397.24 kB | Adobe PDF | View/Open |
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