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http://nopr.niscpr.res.in/handle/123456789/57487| Title: | Synthesis, crystal structure and thermolysis kinetics of [Co(H2O)6](ClO4)2.(HMTA)2.2H2O (HMTA = hexamethylenetetramine) |
| Authors: | Singh, Chandra Prakash Singh, Abhishek Nibha Daniliuc, Constantin G Kumar, Bharat Singh, Gurdip Rao, D P |
| Keywords: | Cobalt compound;Crystal structure;Thermolysis;Kinetics of explosion |
| Issue Date: | May-2021 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | A new compound, [Co(H2O)6](ClO4)2.(HMTA)2.2H2O; HMTA = hexamethylenetetramine) has been synthesized and characterized with the assistance of X-ray crystallography, elemental analysis, FT-IR spectroscopy, TG-DTA and DSC (N2 atmosphere). Both TG data model-fitting method as well as method of model free isoconversional have been employed to observe the kinetics of thermolysis of the compound. In order to understand the effect of sudden high heat, measurements of explosion delay are undertaken at regular five unique temperatures and the kinetics of explosion has also been explored using Arrhenius equation. |
| Page(s): | 676-681 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.60A(05) [May 2021] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 60A(5) 676-681.pdf | Main Article | 1.05 MB | Adobe PDF | View/Open |
| IJCA 60A(5) 676-681_Suppl Data.pdf | Supplementary Data | 231.5 kB | Adobe PDF | View/Open |
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